Lithography (from the Greek lithos = stone, graphos
= writing) is the art of printing on stone. It was
invented about 1796 by Aloys Senefelder, a citizen of
Munich. The precess is based on the mutually repellent
character of oil and water.
First an image is drawn in reverse on a smooth slab
of limestone, using a kind of greasy chalk which
interacts with the lime of the stone beneath it. The part
of the surface which has not been drawn on is
desensitized to grease by treatment with a solution of
gum arabic and acids. Once the image has actually
penetrated into the stone the drawing is washed off
the surface with turpentine and water. Greasy printing
ink will then adhere to the stone only where the image
has been drawn and will be rejected by the rest of the
surface, which is kept moist with water. Although the lithographic stones are heavy and expensive, they have the advantage of being usable over and over by the simple process of repolishing the surface after a number of prints have been pulled off, since the image is fixed with in the stone itself. In all, several hundred fine proofs can come from each stone.